I depends on what you mean by INV.
On some Chinese (AUREX, Staples) calculators
the second function key is marked as INV. If that is the key you have in mind, on Casios it is the [SHIFT] key. On Sharps it is marked as [2ndF]
If you have in mind the multiplicative inverse (the reciprocal) then your calculator has such a key and it is marked [x^-1]. It the key represented on the following table at the intersection of the 2nd column and the 9th line (RECIPROCAL)
If you are thinking about the inverse of functions, then know that each function shares the same physical key as its inverse. For example to access the arcsine (the function inverse of sine) you press the [SHIFT] key before [SIN]. On the calculator you will notice that near the [SIN] key and to its left there is [SIN^-1].
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